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Hydrogen bond/TalkArch2015

Smokefoot: ←Created page with '==Lewis acid/base== Under 'Definitions and general characteristics' the article stated that "the donor is a Lewis base". The hydrogen bond donor is a proton don...'


==Lewis acid/base==

Under 'Definitions and general characteristics' the article stated that "the donor is a Lewis base". The hydrogen bond donor is a proton donor or electron pair acceptor, i.e. it is a Lewis acid, not base. The proton acceptor is the base. Changed accordingly. <!-- Template:Unsigned IP --><small class="autosigned">—&nbsp;Preceding [[Wikipedia:Signatures|unsigned]] comment added by [[Special:Contributions/2A02:8071:AB5:7A00:D49E:1A5A:7F78:DDAB|2A02:8071:AB5:7A00:D49E:1A5A:7F78:DDAB]] ([[User talk:2A02:8071:AB5:7A00:D49E:1A5A:7F78:DDAB#top|talk]]) 19:26, 11 August 2019 (UTC)</small> <!--Autosigned by SineBot-->

==Hydrogen bond strength==
*) What is the source for the values of the hydrogen bond stregnths (enthalpies)? The accepted value for the H2O...H2O in liquid water is ~ 11 kJ/mol, as was measured by Monosmith & Walrafen (see J. Chem. Phys. 81, 669 (1984)) using Raman spectroscopy.<br />
You'll be surprised, but despite its involvment in many water based reactions and biological reactions there is no data regarding the hydrogen bond strengths around the proton! I have added data from a recent article by Markovitch & Agmon that has directed this issue for the first time in liquid water. [[User:omermar|omermar]] 23/03/07

==SI-units==

Plz, use SI-units! Convert the kcal values kJ.

:done, using 1kcal = 4.186kJ then rounding to nearest whole number. Hopefully this is appropriate; frankly, I think those values ought to be sourced anyhow, and will generally vary quite a lot (according to the ionic strength of the medium, and so on) [[User:Philbradley|Philbradley]] 00:58, 12 November 2006 (UTC)

==Lone pairs and HBr==
The force of attraction b/w hydrogen atom of one molecule and highly electronegative atom of nearby molecule is called hydrogen bonding

I think most people tend to think of charge as not able to be less than the fundamental electronic charge, but as often much more (as in "Do not enter! High Voltage!"). So I think it's misleading and/or unhelpful to call partial charges "strong" without mentioning that they are indeed partial or providing other guidance as to how strong "strong" is.

Doesn't HBr have three lone pairs of electrons, not two? I don't find the article's description of why HBr has weaker hydrogen bonding that compelling; theoretically an individual HBr molecule could form four hydrogen bonds, right? The catch is that in a pure HBr solution, there are only as many H molecules as HBr molecules so the total number of bonds to be formed is limited by the H molecules, leaving each molecule with a total of two...

: A hydrogen bond only forms when the H atom is attached to either an F,O, or N atom, and is "sufficiently close" to another H atom also attached to an F,O or N atom. The reason is because the F, O and N atoms are very electronegative and their nuclei are very small and (and so the charge density is relatively high). The high electronegativity atom draws the electron away from the hydrogen atom, leaving the proton relatively exposed. The proton (slightly positive in charge) can now approach an electronegative atom, and form the "hydrogen bond". It has to approach an F,O or N atom, because (you can think of it this way) their nuclei are about the same size as the exposed proton, which means the hydrogen bond formed will be a good fit. This is sort of a hand-wavy explanation, but the essentials are all here. Yes, the hydrogen atom does participate in other intermolecular forces, but they aren't anywhere as strong as what we typically think as "hydrogen bonding" - as such, they aren't as important. [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)
:*Also, the Lewis dot diagram for HBr does indeed indicate that Br has 3 lone pairs. However, it is important to recognize that these "lone pairs" are only used as a heuristic to understand the organizational structure that is at the heart of chemistry. In fact, quantum mechanical calculations have shown (for example, the water molecule), there are actually ''no'' "bunny ears" sticking out from the O atom which are often used to represent the two lone pairs there. The chemistry of water just behaves as if it did, and so using lone pairs to designate this should be understood as strictly a tool. [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)
:* The "catch" that you mentioned has doesn't have much to do with the lack of hydrogen bonding for HBr. It has to do with the fact that the Br atom is very big. Even if the proton from H can hydrogen bond to it, the charge would be spread out over such a large area that the resulting bond would be very very weak. Keep in mind, however that the hydrogen bonds will form and break very frequently if the temperature is high enough. You might be interested to know, for example, that HF forms hydrogen bonds, and in fact, it is possible for HF to form rings of 5 molecules, all bonded together with hydrogen bonds! Granted, the bonds will break and spontaneously form other structures. [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)
:*And yes, I agree with your first paragraph, but I think in this context it isn't necessary to introduce the complication behind how electronegativities are derived. [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)

==Proposal for Clarification==
I think we should mention on the page somewhere that the hydrogen bond is not necessarily intermolecular. It can be intramolecular as well. Consider the compound H2NCH2CH2CHO for example (1-aminopropanal). The H atom attached to the N atom can hydrogen bond to the aldehyde end! [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)

True - proteins are good example as well (perhaps the reader may connect more redily with this example and there is plenty on the web about these H-bonds).

==Add relative hydrogen bond strengths==
Can someone look up in a table the range relative strengths of hydrogen bonds in these configurations? [[User:HappyCamper|HappyCamper]] 05:17, 28 Mar 2005 (UTC)
F-H ..... H-F
F-H ..... H-O-R
F-H ..... H-N-R
R-O-H ..... H-O-R
R-O-H ..... H-N-R
R-N-H ..... H-N-R

== Diagram is wrong ==

The picture for this article shows water molecules all in a jumble. Hydrogen bonding does not allow the water to bunch up in the patterns in the picture - it prefers that the hydrogen lie on the straight line drawn between the two heteroatoms. Basically, the H-bond angles (the angle from O to H to O) should be close to 180˚ as possible. If a Hydrogen bond angle deviates from 180˚ by more than 30˚, the strength of the bond goes to zero and the hydrogen bond disintegrates. (this is how water evaporates)
:What do you think of [https://ift.tt/3d0DmBq this diagram]? --[[User:JWSchmidt|JWSchmidt]] 00:18, 6 October 2005 (UTC)

:: I think the diagram in this ''aricle'' is fine because it shows dynamic nature of "transient" H-bonds in liquids. The H-bonds are more perfect in solids, but the actual distributions of such angles in molecular crystals are rather broad, and their maxima are sometimes not 180 degrees. [[User:Biophys|Biophys]] 06:00, 6 November 2006 (UTC)

:The molecules are in a jumble because this is a picture of water molecules in the liquid phase, which is naturally "jumbled". Hydrogen bonds are much less "rigid" than people think. Even if the minimum energy configuration has an angle of 180 deg, the molecules are constantly rotating and translating (especially in the liquid phase), which results in a broad distribution of angles. The higher the temperature, the less "perfect" the bonding pattern, due to the increasing importance of entropy. -- [[User:Itub|Itub]] 14:41, 7 November 2006 (UTC)

== Consistent Dimensions ==
In the introduction, in different contexts, two different units are given for H-bond energies, kcal/mol and kJ/mol. Obviously it's better if only one unit is adopted, or values are given in both units. [[User:99of9|99of9]] 23:52, 7 November 2005 (UTC)

== I think there is an error on this page! ==

I could be very much mistaken but I believe the following data in the main article is wrong:

O—H...:N (7 kcal/mol)
O—H...:O (5 kcal/mol)
N—H...:N (3 kcal/mol)
N—H...:O (2 kcal/mol)

Should it not read as follows?

O—H...:N (7 kJ/mol)
O—H...:O (5 kJ/mol)
N—H...:N (3 kJ/mol)
N—H...:O (2 kJ/mol) <span style="font-size: smaller;" class="autosigned">— Preceding [[Wikipedia:Signatures|unsigned]] comment added by [[Special:Contributions/88.107.147.126|88.107.147.126]] ([[User talk:88.107.147.126|talk]]) </span><!-- Template:Unsigned IP -->

----

Please provide a source. --[[User:JWSchmidt|JWSchmidt]] 13:55, 6 December 2005 (UTC)

:I can't find the original source where I got the initial 4 values, so I rechecked two of them. For '''NH<sub>3</sub>''' (N-H...:N), the value is about 3.3kcal/mol (Solomons, T.W. Graham (1988). ''Organic Chemistry'', 4th Ed. John Wiley & Sons, p88). But for '''H<sub>2</sub>O''' (O-H...:O), the value seems to vary considerably. Some published values are 8.7 kcal/mol (Solomons, 1988) and 5.58 kcal/mol (Suresh, S.J., Naik V.M. "Hydrogen bond thermodynamic properties of water from dielectric constant data", ''J. of Chemical Physics'', 1 Dec 2000, 113, 21). Some other H-OH...OH<sub>2</sub> energy values from the internet are: 4.7-5 kcal/mol [https://ift.tt/2KKoV8v], 6.6 kcal/mol [http://csb.stanford.edu/levitt/Levitt_JMB88_Aromatic_Hbond.pdf]), and 6 kcal/mol [https://ift.tt/35hrGHN]. According to the paper by Suresh a wide range of values from 3-8 kcal/mol have been reported, and different techniques are used (e.g. IR absorption, NMR shift, X-ray, Neutron diffraction). Hence the value of 5 kcal/mol stated in the original reference is probably just an approximate value. (Note: 1 kcal/mol = 4.1868 kJ/mol) [[User:Nathaniel|Nathaniel]] 07:45, 7 December 2005 (UTC)
:Thanks for checking into this. I'm not a chemist, but it makes sense to me that it would be hard to measure the energy and that it would be dependent on conditions during the experiment. --[[User:JWSchmidt|JWSchmidt]] 17:48, 7 December 2005 (UTC)

But they are still much weaker than covalent bonds. [[User:Biophys|Biophys]] 06:02, 6 November 2006 (UTC)

The estimates of H-bond energy should be described more carefully. First, is it free energy or enthalpy? Second, energies of H-bonds are different in vacuum and in different media. Third, energies of H-bonds could correspond either to enthalpy of sublimation or enthalpy of fusion. [[User:Biophys|Biophys]] 06:36, 6 November 2006 (UTC)

== References ==

I suggest adding some external links from this page. [[User:Semi Psi|Semi Psi]] 01:15, 3 February 2006 (UTC)

==I don't understand, is it right?==
I am citing from the text:
--oxygen, nitrogen or fluorine, are the doners!!!!!???? Or the receivers of the electron!!
--This electronegative element attracts the electron cloud from around the hydrogen nucleus and, by decentralizing the cloud, leaves the atom with a !!!'''positive'''!!!???? partial charge.
--hydrogen bond results when this strong ?positive? charge density attracts a lone pair of electrons on another heteroatom, which becomes the hydrogen-bond acceptor. !?If it attracts should it be the acceptor?! Now it say oxygen, nitrogen or fluorine are the aceptors?! (i think this is rigth)
It seams to me that since the electronegative of hidrogen is samaller then the electronegative of oxygen, nitrogen or fluorine then hidrogen is the doner...--[[User:Paclopes|Paclopes]] 22:19, 24 July 2006 (UTC)

:The donor is the atom that "donates" the hydrogen atom. For example, in ROH ... NR3, the alcohol on the left is donating a hydrogen bond to the amine on the right. [[User:Itub|Itub]] 12:36, 25 July 2006 (UTC)
:Yes. I'd like to extend this answer and say that in H2O, the oxygen can either act as a DONOR by donating a hydrogen to form a hydrogen bond with another molecule, but it could very well act as an ACCEPTOR when one of its lone pairs (pairs of electron not participating in a covalent bond) accepts a hydrogen from another molecule. [[User:omermar|omermar]] 24/03/07

==Water Beading==
I think in the water section someone should add that hydrogen bonding is the reason that water beads and does not just stay flat when spilled or put on a flat surface. All the water molecules are weakly bonded to eachother and can easily be pushed apart if you push the bead flat.[[User:Kniesten|Kniesten]] 18:07, 6 September 2006 (UTC)

:This is a strange way of saying things. Yes the ultimate cause is H-bonding but the usual explanation is ''surface tension''(, due to the cohesion of water, due to H-bonding). -User: Nightvid

== -CCl3 ==

Not only just N O and F can form hydrogen bond but also -CCl3

For example, chloroform has hydrogen bond.

:I've added this information to the article, but remember that you can edit it yourself. This is a wiki, after all! --[[User:Itub|Itub]] 12:53, 20 October 2006 (UTC)


==Theory, covalent nature, references==
About this : "The initial theory of hydrogen bonding proposed by Linus Pauling suggested that the hydrogen bonds had a partial covalent nature. This remained a controversial conclusion until the late 1990's when NMR techniques were employed by F. Cordier et al. to transfer information between hydrogen-bonded nuclei, a feat that would only be possible if the hydrogen bond contained some covalent character." and the reference given (Cordier et al., J. Magn Res. 1999, 140, 510-512):
I have just looked at this article and it is clearly written in it that other examples of J coupling through hydrogen bonds were known at least one year before them. The most ancient article about this phenomenon seems to be : A. J. Dingley and S. Grzesiek, J. Am. Chem. Soc. 120, 8293–8297 (1998). I hesitated to modify the article myself as I am not sure to understand: is the observation of such a coupling an evidence of the covalent nature of the hydrogen bond ? Or is there something new and decisive on this question in the article of Cordier et al. ? I wonder because they don't claim it at all in their article...

:Other articles that might be relevant (I haven't read any of them, but they were cited in Weinhold and Landis's ''Valency and Bonding'', Cambridge University Press, 2005):
*Summers, MF. J Am Chem Soc 114, 4391 (1992)
*Wütrich K. Proc Natl Acad Sci USA 95, 14147 (1998)
*Shenderovich, SN et al. Ber Bunsenges Phys Chem 102, 422 (1998)
*Cornilescu JS. J Am Chem Soc 121, 2949 (1999)
*Wang YX. J Biomol NMR 14, 181 (1999)

:There have also been discoveries of long-range quantum-mechanical phase coherence that have been used as evidence of the covalent character of the H-bond:
*Isaacs ED et al. Phys Rev Lett 82, 600 (1999); Science 283 (1999)

:I think it would be best not to try to attribute the discovery of evidence of covalent character in hydrogen bonds to any specific author in the article text, because it can be controversial. We can cite some of these references, of course, or a more indirect source such as Valency and Bonding (p. 583). --[[User:Itub|Itub]] 09:54, 3 April 2007 (UTC)

==Hydrogen Bond Angles==
Would it be feasible to add some more discussion of typical donor-hydrogen-acceptor angles? I know that there is often significant variation, however many geometric analysis software packages such as VMD require a user to input distance and angle values to determine the existence of hydrogen bonds given a set of molecular positions such as a box of water or a protein structure. A few brief comments in this regard would be very helpful. Example: typical donor-acceptor distances are near 3+/-0.2 A with donor-hydrogen-acceptor angles near 180+/-30 degrees.<br />
[[User:Paul.raymond.brenner|Paul.raymond.brenner]] 16:30, 25 April 2007 (UTC)
:You are welcome to add them, just try to add a reference for the values if possible. --[[User:Itub|Itub]] 08:21, 26 April 2007 (UTC)

:You may recieve some analysis I did on this point. Visit my page (https://ift.tt/2KKoOd5) to get my email. Omermar @ 28/2/2008 <small>—Preceding [[Wikipedia:Signatures|unsigned]] comment added by [[User:Omermar|Omermar]] ([[User talk:Omermar|talk]] • [[Special:Contributions/Omermar|contribs]]) 17:39, 28 February 2008 (UTC)</small><!-- Template:Unsigned --> <!--Autosigned by SineBot-->

== "Carbon can form hydrogen bonds" <- disputed ==

"Chemistry", Gregory M. Williams, John A. Olmsted.

"Carbon never forms hydrogen bonds".
[[User:Contributer314|Contributer314]] 12:00, 27 May 2007 (UTC)

:This is a generalization on the part of the book. Carbon ''usually'' doesn't participate in H-bond formation. However, the dissociation of the acid HCN in water shows that it must be happening. -User: Nightvid

==Why not chlorine?==
My table shows nitrogen and chlorine both having electronegativities of 3.0 - so why can't a H-Cl bond produce hydrogen bonding? Something to do with a larger atomic radius from being in the higher period? [[User:Jasonfahy|Jasonfahy]] 19:06, 29 May 2007 (UTC)
:The lone pairs of electrons on the Cl are in the third shell, unlike N, O, and F. They are thus spread out more and don't have a concentrated negative charge density, which is necessary for H-bond formation. -User: Nightvid

In some electronegativity scales, the EN of chlorine is comparable with that of carbon (There are a very few scales in which it is even less than that of carbon!). Anyway, EN of chlorine is less than that of nitrogen; which is evident from the hydrolysis of NCl<sub>3</sub>. Also, there are N-perchloryl and C-perchloryl bonds.--[[User:Anoop.m|Anoop.m]] ([[User talk:Anoop.m|talk]]) 08:42, 15 July 2010 (UTC)

In silico experiments gives the charge distribution in CCl<sub>4</sub>. It shows negative charge is located on carbon (-0.27) and a small positive charge (+0.07) on chlorine. the H-Cl bond dipole is 1.03 and that of H-C is 1.13. So carbon should be more electronegative than chlorine. --[[User:Anoop Manakkalath|Anoop Manakkalath]] ([[User talk:Anoop Manakkalath|talk]]) 10:46, 18 March 2014 (UTC)

== Hidden content ==

There's some "hidden" content in the Advanced theory of the hydrogen bond section, enclosed in comment &lt;!-- --&gt; tags. Why were these texts removed? --[[User:Freiddy|<font color="#458701" face="Lucida Sans Unicode">Freiddie</font>]] 19:59, 5 August 2007 (UTC)

:*I commented that text out, because I don't understand any of it (and I have close to 40 years of experience in research in intermolecular forces). I did not remove the text altogether, because of the chance that the original author can explain what it means. In that case we can reinsert some of this text after some discussion and clarification. However, you are the first one to react. I assume you don't know either what a ''metric dependent electrostatic scalar field between two or more intermolecular bonds'' is and what its relation is to hydrogen bonding? --[[User:P.wormer|P.wormer]] 12:32, 7 August 2007 (UTC)

:: I hardly know what that statement means when all those "slightly understood" words are put together in one phrase. I'm merely puzzled by the extra spaces in the text at the end of the section (I thought it was just some extra blank space until I edited it to remove it, when I realized that it was not a blank space after all). --[[User:Freiddy|<font color="#458701" face="Lucida Sans Unicode">Freiddie</font>]] 15:52, 8 August 2007 (UTC)

== Confusion with dipole-dipole interactions ==

Someone had added the statement "this can be explained due to the fact that hydrogen bonds are present in H<sub>2</sub>O due to the difference in electro negativity, 1.4(making it polar) as opposed to 0.4 of a difference in H<sub>2</sub>S. this means hydrogen bonds do not occur in H<sub>2</sub>S, because it is non polar giving it a lower boiling point than H<sub>2</sub>O." under "hydrogen bonding phenomena", which I have now removed. I think this is caused by a confusion between H-bonding and dipole-dipole forces. After all, N and Cl have the same Pauling electronegativity and yet NH<sub>3</sub> has an elevated boiling point while HCl does not. There are many other factors determining whether hydrogen bonds can form besides molecular dipole moments. [[Special:Contributions/69.140.12.180|69.140.12.180]] ([[User talk:69.140.12.180|talk]]) 15:13, 3 May 2009 (UTC)Nightvid

Regarding the confusion of concepts the article states : The name hydrogen bond is something of a misnomer, as it is not a true bond but a particularly strong dipole-dipole attraction.--[[Special:Contributions/188.27.144.144|188.27.144.144]] ([[User talk:188.27.144.144|talk]]) 10:58, 5 December 2013 (UTC)

== I don't understand ==

why Phosphorus can form PCl5 and PCl3 but nitrogen only can form NCI3? <span style="font-size: smaller;" class="autosigned">—Preceding [[Wikipedia:Signatures|unsigned]] comment added by [[Special:Contributions/203.82.92.129|203.82.92.129]] ([[User talk:203.82.92.129|talk]]) 06:29, 16 August 2009 (UTC)</span><!-- Template:UnsignedIP --> <!--Autosigned by SineBot-->

This is discussed in the articles [[Octet rule]] and [[Hypervalent molecule]]. [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 14:17, 16 August 2009 (UTC)

== Proton bouncing? ==

It seems that a "proton resonance" occurs in organics with [-(C-OH)=(CH)-(C=O)-] moieties, where the H may bounce back and forth between the two oxygens. Pardon my ignorance, but is this a general phenomenon? Namely, can the H+ easily jump across an H···H bond and covalently bind to the negative atom?<br/>This seems formally possible if several H+ do the jump at the same time, e.g. in a ring of 2 or more water molecules, each donating an H+ to the next one; and/or if there are other simultaneous bond rearrangements, e.g. a swap of the C=O and C-O bonds in two hydrogen-bonded carboxyl groups. Can these swaps actually occur? If so, how widespread is this phenomenon? What are the energy barriers for such swaps? Thanks, and all the best, --[[User:Jorge Stolfi|Jorge Stolfi]] ([[User talk:Jorge Stolfi|talk]]) 14:19, 17 November 2009 (UTC)

:I think the phenomenon you are trying to describe is tautomerism. See the articles on [[tautomer]] and [[keto-enol tautomerism]]. [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 16:29, 17 November 2009 (UTC)
::Yes, thanks, that is what I was thinking of in the first sentence of my query. But the actual question is whether this occurs (a) across different molecules that are connected in a ring by hydrogen bonds, and/or (b) internally between the =O and -OH of a carboxyl group. All the best, --[[User:Jorge Stolfi|Jorge Stolfi]] ([[User talk:Jorge Stolfi|talk]]) 18:05, 17 November 2009 (UTC)

:::In general I think the answer is yes, although the usual term is "proton jump" (or "proton hop") rather than "proton resonance" or "bounce". Also I assume your H···H bond was intended to be an O···O bond. Another example of the phenomenon is the [[Grotthuss mechanism]] for conductivity of acids by proton jumps (or "hops"). [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 00:16, 18 November 2009 (UTC)
::::Thanks! (I meant H···O bond, of course!) --[[User:Jorge Stolfi|Jorge Stolfi]] ([[User talk:Jorge Stolfi|talk]]) 00:33, 18 November 2009 (UTC)

== F-H..F bond strength value. ==

Today user 128.192.14.178 changed the value of the F--H..F bond strength from 155 kJ/mol to 168 kJ/mol, which was reverted by Tetracube with a request for a source. However I note that the value in kcal is 40 kcal/mol which is consistent with 168 kJ/mol (using 1 kcal = 4.184 kJ), so I wonder if the first user just assumed (or checked) that the kcal value is correct and changed the kJ value accordingly. 155 kJ would be 37 kcal. I tried to check which units are used in the source article (usually they are in kcal) but cannot access Chem. Soc. Revs. - can someone please check and then change the converted value with a note here?

A more reliable value may be 38.6 kcal/mol (or 161.5 kJ/mol) measured using [[ion cyclotron resonance]] by J.W. Larson and T.B.McMahon, Inorg. Chem. 23, 2029 (1984). I think we should just use this value.

Finally the line of text just above this value says that "Hydrogen bonds can vary ... to extremely strong (>155 kJ/mol)." I do not understand the > sign here, since I have never heard of a hydrogen bond stronger than F--H..F. Can we just say 155 (or 160) without the ">"? [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 23:18, 19 June 2010 (UTC)
:I have now checked Emsley's 1980 paper in Chem. Soc. Revs. The value is given as > 155 kJ, but it is only a thermochemical estimate using a theoretical lattce energy, and the lowest value in a table with 10 other estimates as high as 243 kJ. Emsley's comment on all these values is that "none is sufficiently reliable to be quoted in preference to the rest".
:The later Larson-McMahon value of 38.6 kcal (161.5 kJ) on the other hand is a direct experimental ICR measurement which I will now insert into the article. [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 20:58, 26 June 2011 (UTC)

== Deuterium Bonds ==

There ought to be a mention of deuterium bonding and how it is stronger than hydrogen bonding (which explains why [[heavy water]] is more viscous than normal water). [[User:Stonemason89|Stonemason89]] ([[User talk:Stonemason89|talk]]) 00:49, 26 August 2010 (UTC)

==Units for H-bond length==
Looking at the bond lengths listed in the "Bonding" section, I see that they are in picometers. Wouldn't it be more appropriate to put them in angstroms, particularly in the case of protein/nucleic acids? While picometers may be a better SI unit, modern parlance is to describe bond lengths in angstroms (no particular reference for this observation, though I can try to track one down).
--[[User:Andrek82|Andrek82]] ([[User talk:Andrek82|talk]]) 15:47, 26 July 2011 (UTC)
:It's fine, both units are widely used for bond lengths. --[[User:Rifleman 82|Rifleman 82]] ([[User talk:Rifleman 82|talk]]) 17:25, 26 July 2011 (UTC)


==Polar hydrogen incorrect?==
there is a typo on the first paragraph, hydrogen is not polar, the other atom that makes the bond is. The term Polar Hydrogen is incorrect.
[Comment by 76.0.112.58 added on 19 Jan 2013]
:I think it would be more correct to say that there is a polar covalent ''bond'' between the hydrogen and the other atom in the H-bond donor. Individual atoms in a molecule are not usually described as polar. [[User:Dirac66|Dirac66]] ([[User talk:Dirac66|talk]]) 20:57, 20 January 2013 (UTC)

==Some grammar tweaks and one material change==
This is a very good article and highly readable for lay persons like me. I've made a handful of grammatical and usage changes where the text tripped my eye: I changed "somewhat of a misnomer" in the first paragraph to "something of a misnomer"; I changed "as is the case of liquid water" to "as is the case with liquid water" and fixed one or two run-on sentences.

I made one material change that may rankle. In the "Advanced theory of the hydrogen bond" section, I changed "In 1999, Isaacs et al. proved..." to "In 1999, Isaacs et al. showed..." If anyone feels strongly opposed to this change, I won't object to changing it back. I think it's a good habit to avoid "prove" and "proof" and so on in such contexts where "showed" or demonstrated" or "showed clearly and convincingly" will serve equally well. [[User:Rt3368|Rt3368]] ([[User talk:Rt3368|talk]]) 06:30, 10 April 2013 (UTC)

== Quantitative aspects rather missing ==

This article is rather qualitative one. It does not specify how the strength of the bond is determined. Other missing aspects is the connection with macroscopic properties like [[virial coefficient]]s and the foundational base of this concept.--[[Special:Contributions/188.27.144.144|188.27.144.144]] ([[User talk:188.27.144.144|talk]]) 12:03, 5 December 2013 (UTC)

April 30, 2020 at 08:13AM

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